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KMID : 1059519940380080598
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Journal of the Korean Chemical Society
1994 Volume.38 No. 8 p.598 ~ p.602
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Light-Induced Electron Transfer Reactions in FeⅡ-CoⅢ Binuclear Complexes
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Lee Gyu-Hwan
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Abstract
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Light-induced electron transfer reaction within binuclear complex (NC)5FeⅡ-L-CoⅢ(NH3)5 was studied with steady-state photolysis and the rate constants were measured for various bridging lignands. klight and quantum yields for BP, PHEN, DAP having conjugation between metal binding sites were about 3×10-2 sec-1 and 1, and for BPEA having no conjugation were about 2×10-4 sec-1 and 0.03. Light-induced electron transfer reaction within binuclear complex was proved to be the chemical mechanism which had charge transfer excited state MLCT*.
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